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    $a 10.1016/j.lithos.2023.107393 $2 DOI
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    $a A petrochronological study of Fe–Ti oxides in rodingites of the Western Carpathians, Slovakia $f Juraj Butek, Damien Dufourcau ... [et al.]
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    $a Rodingitization is the metasomatic transformation of mafic lithologies into rodingite, a Ca-rich and Si-poor rock associated with serpentinized ultramafic bodies. Serpentinization and rodingitization occur simultaneously but it remains challenging to obtain absolute ages on these events in order to identify the geodynamic setting of their formation. In this study, we investigate rodingites from an occurrence in the Western Carpathians with the aim to define the timing of rodingite formation during the tectono-metamorphic evolution of the Carpathian Orogen. The rodingites consist mainly of vesuvianite, diopside, garnet and chlorite. They are noticeably characterized by the presence of Fe–Ti rich aggregates composed of ilmenite, rutile, titanite and calcite. Textural relationships and chemical compositions of the investigated Fe–Ti minerals document their hydrothermal-metamorphic origin. These minerals are characterized by considerable rare earth element (REE) concentrations with prevailing positive Eu anomaly, which presumably derives from the plagioclase-rich protolith of the investigated rodingites. Moreover, the similarity of REE patterns between the analysed phases suggests that the REE concentrations in Fe–Ti minerals are controlled by the immobility and availability of these elements in the system. A particular lamellae texture composed of rutile and calcite originated from titanite destabilization. The titanite destabilization was triggered by cooling, silica leaching and influx of CO2-rich fluids. In situ U–Pb dating of rutile, which have formed by retrograde breakdown of titanite during rodingitization, yields a crystallization age of 102.6 ± 19.9 Ma. This age is in good agreement with Cretaceous ages of the regional alpine metamorphic evolution reported in the literature and suggests that the rodingitization and serpentinization processes took place during the exhumation and cooling of the accretionary wedge resulting from the closure of the Meliata Ocean.
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    $a Gadolinium-dominant monazite and xenotime $e selective hydrothermal enrichment of middle REE during low-temperature alteration of uraninite, brannerite, and fluorapatite (the Zimná Voda REE-U-Au quartz vein, Western Carpathians, Slovakia) $f Martin Ondrejka ... [et al.]
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    $a Monazite-(Gd), a new Gd-dominant mineral of the monazite group from the Zimná Voda REE-U-Au quartz vein, Prakovce, Western Carpathians, Slovakia $f Martin Ondrejka ... [et al.]
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    $a Neobyčajné chemické zloženie sfaleritov z výskytu Brezno-Za dolinou, Slovensko, Nízke Tatry, Západné Karpaty $f Eva Hoppanová ... [et al.]
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    $a The studied mineralization is located on the eastern slopes of Lopejské Čelno valley, south of the Lopej village (cadastral area of Podbrezová village, Central Slovakia). The U occurrence was described and classified as U-Cu stratiform mineralization. The mineralization is located in the Ľubietová Zone of Veporic Unit, and is bound to the arkosic sandstones containing Permian volcanoclastic material. The host rock of mineralization underwent low-grade metamorphism and limonitization. Lens shaped ore bodies are characterized by disseminated pyrite, rutile, chalcopyrite, leucoxene and metatorbernite. Small cavities and cracks in rock are also filled and/or coated by goethite, Mn oxides and malachite. Uranium is irregularly distributed within the host rock and is bound to the U-Ti oxides, brannerite and torbernite/metatorbernite. Brannerite and leucoxenized U-Ti oxides are the only one primary uranium U4+ minerals, for the first time identified in studied occurrence. Brannerite forms clusters of needle-like crystals (up to 100 μm in size). It occurs in close spatial and genetic association with U-Ti oxides, rutile, leucoxene and clay minerals. Chemical composition of brannerite and U-Ti oxides differs in ratio of U/(U + Ti): from 0.22 to 0.29 apfu for brannerite and from 0.09 to 0.22 apfu for U-Ti oxides. Metatorbernite forms light green crystals, typically occurs in small cavities and fractures in rock. It shows an unusual light green luminescence under UV radiation. The average chemical composition of metatorbernite can be expressed by empiric formula (Cu0.75Ba0.06Ca0.03K0.04Al0.02Mg0.01Fe0.01)Σ0.94 (UO2)Σ2.00 (PO4)Σ2.01 (H2O)8. Occasionally torbernite/metatorbernite directly replaces single crystals of apatite.
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