Počet záznamov: 1
Germanium and rare earth elements in topsoil and soil-grown plants on different land use types in the mining area of Freiberg (Germany)
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$a 10.1016/j.gexplo.2017.01.008 $2 DOI 100 $a 20170524 2017 m y slo 03 ba 101 0-
$a eng 102 $a NL 200 1-
$a Germanium and rare earth elements in topsoil and soil-grown plants on different land use types in the mining area of Freiberg (Germany) $f Oliver Wiche ... [et al.] 330 $a The total concentrations and chemical fractionation of Germanium (Ge) and selected rare earth elements (REEs) in top soils and soil-grown plants of different land use types (moist grassland, mesic grassland, arable land) were investigated in the post-mining area of Freiberg (Saxony, Germany). The study area covers approximately 1000 km(2) in the south of Central Saxony, and 138 samples from 46 sampling sites were examined. Ge and REEs in soils were partitioned by a sequential extraction procedure into mobile/exchangeable (Fraction 1), acid soluble (Fraction 2), bound to organic matter (Fraction 3), amorphous Fe/Mn-oxyhydroxides (Fraction 4), crystalline Fe/Mn-oxides (Fraction 5) and residual fractions (Fraction 6). Total concentrations of Ge and REEs in soil varied considerably ranging from 1.0 mu g g(-1) to 43 mu g g(-1) for Ge (mean 1.9 mu g g(-1)) and 97 mu g g(-1) to 402 mu g g(-1) (mean 168 mu g g(-1)) for total REE contents, accounting for 17% and 14% to the investigated light REEs La and Nd, respectively and 2.8% and 1.5% to the investigated heavy REEs Gd and Er, respectively. Elements in potentially plant available fractions represented 8% of total Ge and 30% of total REEs, respectively. Soils on moist grasslands characterized as acidic fluvisols and gleysols with high organic matter content contained significantly higher total concentrations of Ge and REEs and higher concentrations of Ge and REEs in the potentially plant available Fractions 1-3 compared to soils of mesic grassland and arable land. Grass species accumulated significantly higher concentrations of Ge than herb species. Highest concentrations of Ge were measured in plant species growing on moist grassland (Phalaris arundinacea: 449 ng g(-1)), while there were no significant differences with regard to the concentrations of REEs in plants among the different land use types. The results of this study indicate that moist grasslands may act as sinks for Ge and REEs. In these soils high amounts of soil organic matter and low pH may foster the retention of labile forms, increasing the pool of Ge and REEs accessible for phytoextraction. However, the species-specific processes involved during the uptake of REEs need to be understood in order to optimize phytomining techniques. (C) 2017 Elsevier B.V. All rights reserved. 463 -1
$1 001 umb_un_cat*0293199 $1 011 $a 0375-6742 $1 011 $a 1879-1689 $1 200 1 $a Journal of Geochemical Exploration $v Vol. 175 (2017), pp. 120-129 $1 210 $a Amsterdam $c Elsevier B.V. $d 2017 606 0-
$3 umb_un_auth*0043145 $a geochémia $X geochemistry 606 0-
$3 umb_un_auth*0258844 $a germanium 606 0-
$3 umb_un_auth*0170191 $a využitie krajiny $X land use $X landscape use 615 $n 574 $a Životné prostredie 675 $a 574 700 -1
$3 umb_un_auth*0253882 $a Wiche $b Oliver $9 20 $4 070 701 -1
$3 umb_un_auth*0259461 $a Zertani $b Viola $4 070 $9 20 701 -1
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$3 umb_un_auth*0259463 $a Achtziger $b Roland $4 070 $9 20 701 -1
$3 umb_un_auth*0242401 $a Midula $b Pavol $p UMBFP09 $4 070 $9 20 $q 1 $f 1989- $T Katedra biológie a ekológie 801 -0
$a SK $b BB301 $g AACR2 $9 unimarc sk 856 9-
$u http://gateway.isiknowledge.com/gateway/Gateway.cgi?GWVersion=2&SrcAuth=Alerting&SrcApp=Alerting&DestApp=WOS&DestLinkType=FullRecord&UT=WOS:000394472600011 $a Link do databázy WoS T85 $x existuji fulltexy
Počet záznamov: 1