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Financial management of firms and financial institutions
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Názov Financial management of firms and financial institutions Podnázov 14th international scientific conference preoceedings Akcia Financial management of firms and financial institutions . medzinárodná vedecká konferencia , 14. , Ostrava , 11.-12.09.2023 Vyd.údaje Ostrava : Vysoká škola báňská - Technická univerzita , 2023. - 131 p. Vydanie 1. vyd. ISBN 978-80-248-4693-4 ISSN 2336-162X (online) Form.deskr. zborníky konferencií Jazyk dok. angličtina Krajina Česká republika URL Link na zdrojový dokument Kategória publikačnej činnosti FAI Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy (1) - PUBLIKAČNÁ ČINNOSŤ kniha
Efficient light-induced pK(a) modulation coupled to base-catalyzed photochromismAut.údajeJohannes Gurke ... [et al.]AutorSpoluautoriBudzák Šimon 1982- (20%) UMBFP08 - Katedra chémieZdroj.dok.
Schmidt Bernd M. (20%)
Jacquemin Denis (20%)
Hecht Stefan (20%)Angewandte Chemie : international edition : a journal of the German Chemical Society. Vol. 57, no. 17 (2018), pp. 4797-4801. - Weinheim : Wiley-VCH, 2018Kľúč.slováfotoprepínače - photoswitchesfotochromizmus - photochromismangličtinaKrajinaNemeckoSystematikaAnotáciaPhotoswitchable acid-base pairs, whose pK(a) values can be reversibly altered, are attractive molecular tools to control chemical and biological processes with light. A significant, light-induced pK(a) change of three units in aqueous medium has been realized for two thermally stable states, which can be interconverted using UV and green light. The light-induced pK(a) modulation is based on incorporating a 3-H-thiazol-2-one moiety into the framework of a diarylethene photoswitch, which loses the heteroaromatic stabilization of the negatively charged conjugate base upon photochemical ring closure, and hence becomes significantly less acidic. In addition, the efficiency of the photoreactions is drastically increased in the deprotonated state, giving rise to catalytically enhanced photochromism. It appears that protonation has a significant influence on the shape of the ground- and excited-state potential energy surfaces, as indicated by quantum-chemical calculations.Kategória publikačnej činnostiČíslo archívnej kópie43297
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