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Názov Tailoring photoisomerization pathways in donor-acceptor stenhouse adducts: The role of the hydroxy group Aut.údaje Michael M. Lerch, Miroslav Medveď ... [et al.] Autor Lerch Michael M. (10%)
Spoluautori Medveď Miroslav 1971- (10%) UMBFP08 - Katedra chémie
Lapini Andrea (10%)
Laurent Adéle D. (10%)
Iagatti Alessandro (5%)
Bussotti Laura (5%)
Szymański Wiktor (10%)
Buma Wybren Jan (10%)
Foggi Paolo (10%)
Di Donato Mariangela (10%)
Feringa Ben L. (10%)
Zdroj.dok. The Journal of Physical Chemistry A. Vol. 122, no. 4 (2018), pp. 955-964. - Washington : The American Chemical Society, 2018 Kľúč.slová chémia - chemistry density functional theory Form.deskr. články - journal articles Jazyk dok. angličtina Krajina Spojené štáty Systematika 54 URL https://pubs.acs.org/doi/abs/10.1021%2Facs.jpca.7b10255 Kategória publikačnej činnosti ADC Číslo archívnej kópie 44378 Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy PERIODIKÁ-Súborný záznam periodika 
unrecognised
Unsymmetrical benzothiazole-based dithienylethene photoswitchesAut.údajeMichelangelo Bovoloni ... [et al.]Názov Unsymmetrical benzothiazole-based dithienylethene photoswitches Aut.údaje Michelangelo Bovoloni ... [et al.] Autor Bovoloni Michelangelo (15%)
Title Solvent effects on the actinic step of donor-acceptor stenhouse adduct photoswitching Author info Michael M. Lerch ... [et al.] Author Lerch Michael M. (15%)
Co-authors Di Donato Mariangela (15%)
Laurent Adéle D. (10%)
Medveď Miroslav 1971- (10%) UMBFP08 - Katedra chémie
Iagatti Alessandro (5%)
Bussotti Laura (5%)
Lapini Andrea (5%)
Buma Wybren Jan (10%)
Foggi Paolo (5%)
Szymański Wiktor (10%)
Feringa Ben L. (10%)
Source document Angewandte Chemie : international edition : a journal of the German Chemical Society. Vol. 57, no. 27 (2018), pp. 8063-8068. - Weinheim : Wiley-VCH, 2018 Keywords chémia - chemistry solvent effects density functional theory Form. Descr. články - journal articles Language English Country Germany systematics 54 URL Link na plný text Public work category ADC No. of Archival Copy 44355 Catal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Database xpca - PUBLIKAČNÁ ČINNOSŤ References PERIODIKÁ-Súborný záznam periodika unrecognised
Názov Shedding light on the photoisomerization pathway of donor-acceptor Stenhouse adducts Aut.údaje Mariangela Di Donato, Michael M. Lerch ... [et al.] Autor Di Donato Mariangela (15%)
Spoluautori Lerch Michael M. (15%)
Lapini Andrea (5%)
Laurent Adéle D. (10%)
Iagatti Alessandro (5%)
Bussotti Laura (5%)
Ihrig Svante P. (5%)
Medveď Miroslav 1971- (10%) UMBFP08 - Katedra chémie
Jacquemin Denis (5%)
Szymański Wiktor (5%)
Buma Wybren Jan (10%)
Foggi Paolo (5%)
Feringa Ben L. (5%)
Zdroj.dok. Journal of the American Chemical Society. Vol. 139, no. 44 (2017), pp. 15596-15599. - Washington : The American Chemical Society, 2017 Kľúč.slová molekulové fotoprepínače - molecular photoswitches donorno-akceptorové Stenhousove adukty ultra-fast spectroscopy DFT metóda Jazyk dok. angličtina Krajina Spojené štáty Systematika 54 Anotácia Donor-acceptor Stenhouse adducts (DASAs) are negative photochromes that hold great promise for a variety of applications. Key to optimizing their switching properties is a detailed understanding of the photoswitching mechanism, which, as yet, is absent. Here we characterize the actinic step of DASA-photoswitching and its key intermediate, which was studied using a combination of ultrafast visible and IR pump-probe spectroscopies and TD-DFT calculations. Comparison of the time-resolved IR spectra with DFT computations allowed to unambiguously identify the structure of the intermediate, confirming that light absorption induces a sequential reaction path in which a Z-E photoisomerization of C-2-C-3 is followed by a rotation around C-3-C-4 and a subsequent thermal cyclization step. First and second-generation DASAs share a common photoisomerization mechanism in chlorinated solvents with notable differences in kinetics and lifetimes of the excited states. The photogenerated intermediate of URL Link na plný text Kategória publikačnej činnosti ADC Číslo archívnej kópie 41477 Katal.org. BB301 - Univerzitná knižnica Univerzity Mateja Bela v Banskej Bystrici Báza dát xpca - PUBLIKAČNÁ ČINNOSŤ Odkazy PERIODIKÁ-Súborný záznam periodika unrecognised