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Mechanochemically activated saponite as materials for Cu2+ and Ni2+ removal from aqueous solutions
Title Mechanochemically activated saponite as materials for Cu2+ and Ni2+ removal from aqueous solutions Author info L. Petra, P. Billik, Z. Melichová, P. Komadel Author Petra Lukáš (30%)
Co-authors Billik Peter (30%)
Melichová Zuzana 1966- (20%) UMBFP08 - Katedra chémie
Komadel Peter (20%)
Source document Applied Clay Science. Vol. 143 (2017), pp. 22-28. - Amsterdam : Elsevier B.V., 2017 Keywords heavy metal adsorption waste water ílové minerály - clay minerals adsorbenty mechanochémia - mechanochemistry atómová absorpčná spektroskopia - atomic absorption spectroscopy Language English Country Netherlands systematics 546 Annotation Saponites are nanosized layered aluminosilicates from the smectite group of clay minerals, which can be further functionalized to prepare low-cost materials for water purification. Mechanochemical activation of saponite was achieved by high-energy grinding in a planetary ball mill. X-ray diffraction, infrared spectroscopy, scanning electron microscopy, thermal analysis, and the determination of cation-exchange capacity and specific surface area were used to characterize parent and functionalized solids. Prepared adsorbents were used for Cu2+ and Ni2+ removal from aqueous solutions. Compared to the untreated sample, activated saponites had significantly increased capacity to take away metal cations. The equilibrium data showed the maximum of Cu2+ and Ni2+ uptake of 295 and 129 mg/g, respectively. In comparison with the pristine material, the measured values increased by 764% and 170% for Cu2+ and Ni2+ respectively. The formation of reactive Mg(OH)(2) as the saponite decomposition product was also discussed. (C) 2017 Elsevier B.V. All rights reserved. Public work category ADC No. of Archival Copy 39735 Repercussion category WEI, Guangtao - LI, Yunshang - ZHANG, Linye - CAI, Shuya - ZHU, Tong - LI, Zhongmin - MO, Jihua. Synthesis of bentonite-supported Fe(II) and heteropolyacid (HPW) composite through a mechanochemical processing. In Applied clay science. ISSN 0169-1317, 2018, vol. 152, pp. 342-351.
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